Rapid 3D printing of electro-active hydrogels

Abstract

Electroactive hydrogels (EAH) have gained prominence for their unique ability to change shape or size under an electric field, finding applications in biosensors and soft actuators. This study focuses on a tunnelable EAH tailored for high-resolution 3D printing via the micro continuous liquid interface production (µCLIP) process. The resin formulations mainly involve acrylic acid (AA) and 4-hydroxybutyl acrylate (4-HBA). AA, with its carboxyl groups, introduces electroactuation, generating osmotic pressure in the hydrogel matrix. This results in swelling, inducing bending towards the cathode, accentuating the material’s responsiveness. In contrast, 4-HBA offers mechanical resilience, providing an elastic backbone, and ensuring the hydrogel’s applicability. Our results illustrate the hydrogel’s strength, flexibility, and bending capabilities across varied compositions and electric field strengths. Notably, the µCLIP process enabled the 3D printing of our EAH into sophisticated structures, like the lattice. The combination of AA’s electro-responsive traits with 4-HBA’s durability has birthed a material with vast practical implications. This study provides extended potential breakthroughs in soft robotics, wearable electronics, and medical devices, marking a significant stride in the realm of electroactive materials.