Thermo‐responsive polymers for thermal regulation in electrochemical energy devices

Abstract

Abstract Thermo‐responsive polymers have been widely explored because of their diverse structures and functions in response to temperature stimuli. Great attention has been attracted to exploring and designing such polymers composites, which offer tremendous opportunities to build up a systematic understanding of their structure–function relationships and pave the ways for their extensive applications in electronics, soft robotics, and electrochemical energy storage devices. Here, we review the most recent research of thermal regulation in electrochemical energy storage devices (e.g., batteries, supercapacitors) via thermo‐responsive polymers. We summarize how battery components (i.e., electrolytes, separators, electrodes, or current collectors) can be coupled with thermo‐responsive polymers based on different operation mechanisms, such as volume expansion, polymerization, phase reversion, and de‐doping effects, to effectively prevent catastrophic thermal runaway. Different types of thermo‐responsive polymers are evaluated to compare their key features and/or limitations. This review is concluded with perspectives of future design strategies towards more effective thermo‐responsive polymers for battery thermal regulation.