High-performance dual-sensitive flexible sensors based on conductive alginate sponge electrode/polyvinylidene fluoride microporous composite film

摘要

Abstract This work reported a novel dual-sensitive flexible sandwich sensor based on conductive natural biopolymers sponge electrode and polyvinylidene fluoride (PVDF) film with superiorities of high sensitivity, long lifespan and low density. The unique natural biopolymers sponge electrode, consisting of bidisperse magnetic particles and sodium alginate/chitosan (SA/CHI) with physically-crosslinked double-network structure, showed a high response capability to external magnetic fields. Besides, by combining the advantages of SA/CHI sponge electrode (high elasticity and flexibility) and PVDF film (exceptional stiffness and piezoelectricity), the SA/CHI/PVDF composite film also exhibited preferable mechanical strength and strain-dependent electrical property, which can simultaneously satisfy the requirements of high sensitivity detection to external magnetic fields and strains. Specifically, the relative resistance variation of SA/CHI/PVDF-1.00 sensor reached as high as 60.4% under a cycling loading of 240 mT magnetic field. Meanwhile, their electrical responses could also display a significant variation and relatively stable recoverability under periodic stretching, bending or compressing excitations. Afterwards, a potential working mechanism and equivalent circuit model were provided to study the magnetic/mechanic sensitivity of SA/CHI/PVDF sensors. Furthermore, a 4 × 4 SA/CHI/PVDF sensor array was developed to perceive and distinguish both magnetic field and compressive force, which indicated its favorable potential in wearable electronics and soft robotics.