Isosorbide
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Isosorbide is a bicyclic diol derived from renewable biomass sources, particularly from the dehydration of sorbitol obtained from glucose. In materials science and robotics, it serves as a biobased building block for constructing high-performance polymers, epoxy resins, and thermoset materials with enhanced rigidity and thermal stability due to its rigid bicyclic structure. When incorporated into dynamic cross-linking networks, such as those featuring vinylogous urethane bonds, isosorbide enables the creation of recyclable, shape-memory materials that can be reshaped or reprocessed under controlled conditions without sacrificing mechanical integrity. This is particularly relevant for soft robotics and adaptive structures, where actuators, grippers, and structural components benefit from materials that are both mechanically robust and reconfigurable. The significance of isosorbide lies in its sustainability credentials — replacing petroleum-derived monomers with biobased alternatives — while simultaneously delivering materials with competitive performance, supporting the development of environmentally responsible robotic systems and smart material platforms.
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Recyclable Biobased Dynamic Cross-Linking Epoxy Thermosets Containing Vinylogous Urethane Bonds with Shape Memory Properties
Ruhan Yang, Weijie Li, Ruibin Mo, Xinya Zhang
Citations: 9 • 2023