Quantitative analysis of binary and ternary organo-mineral solid dispersions by Raman spectroscopy for robotic planetary exploration missions on Mars

Abstract

, based on the ratio of apparent Raman scattering coefficients, the relative proportion of minerals in binary mixtures can be accurately determined. Regarding the organics, evaluated in clay-rich sediments (Fe-smectite) and crushed rocks of coarse-grained fraction (>100μm), we establish calibration curves in the concentration range 2-20 wt% for non-resonant compounds (L-cysteine, phthalic acid, adenine) and even lower (<1 wt%) for pre-resonant anthracene. Despite large levels of heterogeneity, the Raman analyses of these solid dispersions verify that quantitative Raman analyses can be performed in the context of robotic exploration studies.