Highly efficient Pt–Ru–Co–W quaternary anode catalysts for methanol electrooxidation discovered by combinatorial analysis

Abstract

PtRuCoW quaternary alloy system is explored by a robotic dispenser and combinatorial optical screening method, and some active quaternary electrocatalysts are discovered for methanol oxidation in DMFC. The newly developed PtRuCoW catalysts exhibit superior electrochemical catalytic activity and better electrochemical stability toward methanol oxidation than Pt50–Ru50 binary alloy. A catalyst with Pt43Ru33Co14W10 composition is the most active, demonstrating an enhancement in the activity of ca. 40 ∼ 70% compared with the commercial binary Pt50–Ru50E-TEK catalyst. The enhancement of catalytic activity can be explained by bifunctional mechanism, electronic effect, redox process and cooperative synergic effects of added Co and W metals.