OTHER
Site-to-site peptide transport on a molecular platform using a small-molecule robotic arm
Salma Kassem, Alan T. L. Lee, David A. Leigh, Augustinas Markevicius, Daniel J. Tetlow, Naoyuki Toriumi
- 发表年份
- 2020
- 引用次数
- 14
- 访问权限
- 开放获取
摘要
H NMR. The size of the peptide cargo has no significant effect on the rate or efficiency of transport in either direction. The new operating conditions allow detailed physical organic chemistry of the ratcheted transport mechanism to be uncovered, improve efficiency, and enable the transport of more complex cargoes than was previously possible.
关键词
IsomerizationProtonationMolecular switchChemistryDeprotonationYield (engineering)MoleculeSolventSubstrate (aquarium)Dynamic covalent chemistry
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