River Inflow Dominates Methane Emissions in an Arctic Coastal System

摘要

Abstract We present a year‐round time series of dissolved methane (CH 4 ), along with targeted observations during ice melt of CH 4 and carbon dioxide (CO 2 ) in a river and estuary adjacent to Cambridge Bay, Nunavut, Canada. During the freshet, CH 4 concentrations in the river and ice‐covered estuary were up to 240,000% saturation and 19,000% saturation, respectively, but quickly dropped by >100‐fold following ice melt. Observations with a robotic kayak revealed that river‐derived CH 4 and CO 2 were transported to the estuary and rapidly ventilated to the atmosphere once ice cover retreated. We estimate that river discharge accounts for >95% of annual CH 4 sea‐to‐air emissions from the estuary. These results demonstrate the importance of resolving seasonal dynamics in order to estimate greenhouse gas emissions from polar systems.