A comparison of CMAQ‐based aerosol properties with IMPROVE, MODIS, and AERONET data

摘要

Evaluation of concentrations predicted by air quality models is needed to ensure that model results are compatible with observations. In this study aerosol properties derived from the Community Multiscale Air Quality (CMAQ) model‐simulated aerosol mass concentrations are compared with routine data from NASA satellite‐borne Moderate Resolution Imaging Spectroradiometer (MODIS) sensor aboard the Sun‐synchronous Terra satellite, NASA's ground‐based Aerosol Robotic Network (AERONET), and the ground‐based Interagency Monitoring of Protected Visual Environment (IMPROVE) network. The motivation for this analysis is to determine how best to use these parameters in evaluating model‐predicted PM 2.5 concentrations. CMAQ surface extinction estimates due to scattering at 550 nm wavelength are compared with the IMPROVE nephelometer data obtained from 25 sites within the United States. It is found that model‐predicted surface extinctions bear high correlations with nephelometer measured data. Sulfate fractional aerosol optical depth (AOD) is found to dominate in the northeastern part of the United States; hence ground‐based measurement of sulfate concentrations have been compared with time series of columnar AOD as observed by the MODIS instrument and also with the CMAQ‐predicted tropospheric column values obtained during the June–August period of 2001. CMAQ surface extinctions are found to be relatively higher than the IMPROVE nephelometer observations; however, there is a good agreement between CMAQ AOD trends and AERONET and MODIS data, obtained at the seven AERONET sites located in the eastern United States. CMAQ is also found to capture the day‐to‐day variability in the spatial AOD patterns. Monthly average satellite AOD estimates are found to be higher than the AOD data obtained using the CMAQ‐predicted aerosol concentrations. Seasonal variation of satellite‐measured aerosol intensive property “Angstrom exponent” (a gross indicator of the aerosol size distribution) is presented for four selected sites: one each in the eastern and central parts, and two in the western part of the continental United States. Variability of Angstrom exponent at these four selected sites is analyzed in conjunction with the variation of summertime AOD (observed and modeled), mass concentration (observed and modeled) and modeled SO 4 average concentrations during the summer (June–August) period of the year 2001. Annual time series of Angstrom exponent data at the four selected sites show a large east‐west variation.